期刊目錄列表 - 21~30期(1976-1985) - 第二十八期 (1983)

氨氧化法製備3-腈吡啶和苯甲腈 作者:洪明志、許春峰、陳朝棟、王澄霞(國立臺灣師範大學理學院化學系)

摘要:

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Journal directory listing - Volume 21-30 (1976-1985) - Volume 28 (1983)

Preparation of 3-Cyanopyridine and Benzonitrile by Ammoxidation Author: Jhy-ming Horng, Chuwn-feng Sheu, Chao-tung Chen, Chen-hsia Wang(Department of Chemistry College of Sciences)

Abstract:

3-Cyanopyridine is the intermediate for nicotinamidc and nicotinic acid. Benzonitrile is the intermediate for homosulfamine. A procedure has now been established for the laboratory fluidized-bed ammoxidation of 3-picoline and toluene to form 3-cyanopyridine in 35.2% yield and benzonitrile in 41.5% yield. The effects of reaction temperature, mole ratio of reactants, and amount of catalyst were studied.